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KGAWC(Korea Global Atmosphere Watch Center)

WCC Scope - ToR in GAW report #172
   KMA (Korea Meteorological Administration) has operated the World Calibration Centre for Sulphur hexafluoride (WCC-SF6), one of the central facilities in the World Meteorological Organization / Global Atmosphere Watch (WMO/GAW) programme, since October 2012. The duties of WCC-SF6 as follows:

a) assist WMO members operating WMO/GAW stations to link their sulphur hexafluoride (SF6) observations to the WMO/GAW
reference Scale through comparisons with standards calibrated against the primary/secondary standards maintained
by the Central Calibration Laboratory for SF6;

b) assist the WMO/GAW Scientific Advisory Group (SAG) on Greenhouse Gases in the development of the quality control
procedures required to support the quality assurance of SF6 measurements and ensure the traceability of these
measurements to the corresponding primary standard;

c) maintain laboratory and transfer SF6 gas standards that are traceable to their respective primary standard(s);

d) perform regular calibrations and inter-comparison campaigns involving the WMO/GAW stations/laboratories;

e) assist in provision of training and long-term technical help for WMO/GAW stations; and

f) make public its involvement in the WMO/GAW Programme (e.g. on its websites, in its newsletters, etc.).

WCC-SF6 Laboratory facility
-Working and Travelling standards
WCC-SF6 established several systems for sampling compressed dry natural air and analyzing SF6 to prepare laboratory and transfer gas standards traceable to the WMO/GAW SF6 Reference Scale.
-Cleaning cylinders: 10 L aluminum cylinders are cleaned up with evacuation system, a turbo molecular pump and a heating apparatus more than 12 hours that is able to maintain the residual pressure inside the cylinder less than 0.1 Pa. (Fig. 1(a)).
-Collecting air: Dry natural air sample is collected by an oil free air compressor through a dekabon tube from the top of 40 m height sampling tower. To remove moisture in the air sample, a chemical trap filled with granulated magnesium perchlorate is used. (Fig. 1(b_,(c),(d))
-Analysing SF6: After preparation of compressed air in the cylinders, SF6 mole fraction of the samples are assigned by a gas chromatograph with electron capture detector (GC-μ ECD, Agilent 7890) and five reference gases of the WMO SF6 mole fraction scale maintained by the CCL (in NOAA). (Fig. 2, 3)
Cylinder evacuation system Sampling tower(40m) Air compressor room Air sampling system
(a) Cylinder evacuation system (b) Sampling tower
(40 m height)
(c) Air compressor room (d) Air sampling system

Figure 1. Systems for preparation of compressed dry air in the cylinder

Pre-concentrator SF6 analyzer(GC-ECD) SF6 standards(WMO mole fraction scale)
(a) Pre-concentrator (b) Analytical system (c) NOAA X2014 scale

Figure 2. Analytical system and WMO reference scale (NOAA X2014) to prepare for labotory and transfer standards gases, which are traceable to the WMO reference scale

SF6 Analysis Method
-Method description: Preconcentrator + Back flush
GC-μ ECD (Agilent 7890) is used to assign mole fractions. Configuration of analytical system is as follows:
Gas cylinder → regulator → MFC (Mass Flow Controller) → Pre-concentration → sample injection valve (back flush) → column → detector
-Analytical conditions
Detector μ ECD
Detector temperature 375 °C
Column Alumina 6ft (pre), Alumina 18ft (main)
Sample Flow 100 mL/min
Carrier gas, pressure P5(Nitrogen/Methane), 60 psi
Oven temperature 60 °C
Calibration curve Chromatogram

Figure 3. Calibration curve (left) and chromatogram (right) of the five NOAA SF6 standard gases

- Valve Position (Preconcentrator + Injection valve)

Figure 4. Valve positions during the analysis of SF6 at WCC-SF6 lab

- Two-point calibration is implemented against WMO scale (NOAA-X2014) with the sequence of CRM1-sample-CRM2-CRM1 to monitor the instrument drift.